Mode-coupling theory of the glass transition for confined fluids - Archive ouverte HAL
Article Dans Une Revue Physical Review E : Statistical, Nonlinear, and Soft Matter Physics Année : 2012

Mode-coupling theory of the glass transition for confined fluids

Simon Lang
  • Fonction : Auteur
Rolf Schilling
  • Fonction : Auteur
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Vincent Krakoviack
Thomas Franosch
  • Fonction : Auteur

Résumé

We present a detailed derivation of a microscopic theory for the glass transition of a liquid enclosed between two parallel walls relying on a mode-coupling approximation. This geometry lacks translational invariance perpendicular to the walls, which implies that the density profile and the density-density correlation function depends explicitly on the distances to the walls. We discuss the residual symmetry properties in slab geometry and introduce a symmetry adapted complete set of two-point correlation functions. Since the currents naturally split into components parallel and perpendicular to the walls the mathematical structure of the theory differs from the established mode-coupling equations in bulk. We prove that the equations for the nonergodicity parameters still display a covariance property similar to bulk liquids.

Dates et versions

hal-01667352 , version 1 (19-12-2017)

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Simon Lang, Rolf Schilling, Vincent Krakoviack, Thomas Franosch. Mode-coupling theory of the glass transition for confined fluids. Physical Review E : Statistical, Nonlinear, and Soft Matter Physics, 2012, 86 (2), pp.021502. ⟨10.1103/PhysRevE.86.021502⟩. ⟨hal-01667352⟩
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