A new model for in situ nitrogen incorporation into 4H-SiC during epitaxy - Archive ouverte HAL
Article Dans Une Revue Scientific Reports Année : 2017

A new model for in situ nitrogen incorporation into 4H-SiC during epitaxy

Un nouveau modèle d'incorporation de l'azote pendant la croissance épitaxiale du 4H-SiC

Résumé

Nitrogen doping of 4H-SiC during vapor phase epitaxy is still lacking of a general model explaining the apparently contradictory trends obtained by different teams. In this paper, the evolutions of nitrogen incorporation (on both polar Si and C faces) as a function of the main growth parameters (C/Si ratio, temperature, pressure and growth rate) are reviewed and explained using a model based on surface exchanges between the gas phase and the uppermost 4H-SiC atomic layers. In this model, N incorporation is driven mainly by the transient formation of C vacancies, due to H 2 etching, at the surface or near the surface. It is shown that all the growth parameters are influencing the probability of C vacancies formation in a similar manner as they do for N incorporation. The surface exchange model proposes a new framework for explaining the experimental results even beyond the commonly accepted reactor type dependency.
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Dates et versions

hal-01615178 , version 1 (12-10-2017)

Identifiants

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Gabriel Ferro, Didier Chaussende. A new model for in situ nitrogen incorporation into 4H-SiC during epitaxy. Scientific Reports, 2017, 7, pp.43069. ⟨10.1038/srep43069⟩. ⟨hal-01615178⟩
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