Rhodium(I) complexes of a PBP ambiphilic ligand: Evidence for a metal→borane interaction - Archive ouverte HAL
Article Dans Une Revue Angewandte Chemie International Edition Année : 2006

Rhodium(I) complexes of a PBP ambiphilic ligand: Evidence for a metal→borane interaction

Résumé

To and fro: Diphosphanylborane derivative 1 behaves as a tridentate, ambiphilic ligand towards rhodium(I) fragments (see picture). The presence of metal-→borane interactions in the resulting square-pyramidal complexes is highlighted by structural analyses and DFT calculations. (Chemical Equation Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

Dates et versions

hal-01613262 , version 1 (09-10-2017)

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Sylvain Bontemps, Heinz Gornitzka, G. Bouhadir, Karinne Miqueu, D. Bourissou. Rhodium(I) complexes of a PBP ambiphilic ligand: Evidence for a metal→borane interaction. Angewandte Chemie International Edition, 2006, 45 (10), pp.1611-1614. ⟨10.1002/anie.200503649⟩. ⟨hal-01613262⟩
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