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Article Dans Une Revue Physical Chemistry Chemical Physics Année : 2017

Experimental evidence of charge transfer in a functionalized hexavanadate: a high resolution X-ray diffraction study

Résumé

A high resolution X-ray diffraction study has been carried out on [(C4H9)4N]2 [V6O13{(OCH2)3CCH2OCCH2CH3}2] (V6–C3) at 100 K. The V6 core possesses a negative charge, leading to a strong polarization of the anion. A nucleophilic region localized near the organic moiety and an electrophilic region in the vicinity of the V6 core provide an overall description of charge-transfer behavior.
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Dates et versions

hal-01592027 , version 1 (29-09-2020)

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Xiao Xu, Anne Spasojević-de Biré, Nour Eddine Ghermani, Yongge Wei, Sladjana Novaković, et al.. Experimental evidence of charge transfer in a functionalized hexavanadate: a high resolution X-ray diffraction study. Physical Chemistry Chemical Physics, 2017, 19 (28), pp.18162-18166. ⟨10.1039/C7CP01840A⟩. ⟨hal-01592027⟩
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