Bottom-up assembly of ultrathin sub-micron size metal-organic framework sheets
Résumé
A solution-based two-dimensional interfacial reaction between 5,10,15,20-tetra(4-pyridyl)-porphinato zinc(II) (ZnTPyP, 1) and Cu(NO3)(2)center dot 3H(2)O, 2, results in the assembly of uniform preferentially oriented highly crystalline metal-organic framework nanosheets, NAFS-21 that have sub-micron planar size and mono-molecular thickness
Domaines
Chimie
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