Oxidation of NO into NO2 by surface adsorbed O atoms
Résumé
Plasma-surface interactions are increasingly recognised as a key factor in explaining molecule production and conversion processes. In order to scrutinise such effects well-defined surface and gas phase conditions are required. Hence, the inner surface of a Pyrex tube was treated by a capacitively coupled RF plasma at low pressure. The post-plasma oxidation of gas mixtures containing 1 % NO into NO2 has been studied by means of quantum cascade laser absorption spectroscopy in the mid-infrared spectral range. The plasma pre-treatment experiments with oxygen containing precursors suggest O atom adsorption on the Pyrex tube with a surface density of 2.7 x 1014 cm2. A simple kinetic model was developed and shows good agreement with the measured NO and NO2 gas phase concentrations. In the model a fraction of the surface is considered to be covered with chemisorption sites where atoms and molecules can be adsorbed, whereas they can be removed only by recombination (© 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)