First examples of organosilica-based ionogels : synthesis and electrochemical behavior. - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Beilstein Journal of Nanotechnology Année : 2017

First examples of organosilica-based ionogels : synthesis and electrochemical behavior.

Résumé

The article describes the synthesis and properties of new ionogels for ion transport. A new preparation process using an organic linker, bis(3-(trimethoxysilyl)propyl)amine (BTMSPA), yields stable organosilica matrix materials. The second ionogel component, the ionic liquid 1-methyl-3-(4-sulfobutyl)imidazolium 4-methylbenzenesulfonate, [BmimSO3H][PTS], can easily be prepared with near-quantitative yields. [BmimSO3H][PTS] is the proton conducting species in the ionogel. By combining the stable organosilica matrix with the sulfonated ionic liquid, mechanically stable, and highly conductive ionogels with application potential in sensors or fuel cells can be prepared.

Domaines

Chimie

Dates et versions

hal-01525211 , version 1 (19-05-2017)

Identifiants

Citer

Andreas Taubert, Ruben Löbbicke, Barbara Kirchner, Fabrice Leroux. First examples of organosilica-based ionogels : synthesis and electrochemical behavior.. Beilstein Journal of Nanotechnology, 2017, 8, pp.736-751. ⟨10.3762/bjnano.8.77⟩. ⟨hal-01525211⟩
220 Consultations
0 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More