One-Pot Aerosol Route to MoO3-SiO2-Al2O3 Catalysts with Ordered Super Microporosity and High Olefin Metathesis Activity - Archive ouverte HAL
Article Dans Une Revue Angewandte Chemie International Edition Année : 2012

One-Pot Aerosol Route to MoO3-SiO2-Al2O3 Catalysts with Ordered Super Microporosity and High Olefin Metathesis Activity

Résumé

Aerosol processing coupled with surfactant-templated sol–gel synthesis is used to produce MoO3-SiO2-Al2O3 catalysts. By quenching the sol–gel kinetics by fast drying of the aerosol, molecular-scale dispersion of each component is achieved. The structuring agent generates an organized porosity at the nanoscale. The catalysts have a high specific surface area and outstanding olefin metathesis activity.

Dates et versions

hal-01468413 , version 1 (15-02-2017)

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Damien P. Debecker, Mariana Stoyanova, Frederic Colbeau-Justin, Uwe Rodemerck, Cédric Boissière, et al.. One-Pot Aerosol Route to MoO3-SiO2-Al2O3 Catalysts with Ordered Super Microporosity and High Olefin Metathesis Activity. Angewandte Chemie International Edition, 2012, 51 (9), pp.2129-2131. ⟨10.1002/anie.201106277⟩. ⟨hal-01468413⟩
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