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Article Dans Une Revue European Journal of Mass Spectrometry Année : 2000

Rydberg electron-capture mass spectrometry of 1,2,3,4 tetrachlorodibenzo-p-dioxin

Résumé

A negative-ion creation technique by Rydberg electron capture (REC) is used to ionise 1,2,3,4 tetrachlorodibenzo-p-dioxin (1,2,3,4-TCDD). Negative ions are mass-analysed by a commercial quadrupole mass spectrometer and also by a home-made mass spectrometer using a quadrupole ion trap. From spectra of 1,2,3,4-TCDD a comparison between the REC ionisation technique and two other soft ionisation techniques, electron capture chemical ionisation (ECCI) and the electron monochromator (EM), are discussed.

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Chimie
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Dates et versions

hal-01443465 , version 1 (27-01-2017)

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Michel Carette, Y Zerega, Pierre Perrier, J André, R E March. Rydberg electron-capture mass spectrometry of 1,2,3,4 tetrachlorodibenzo-p-dioxin. European Journal of Mass Spectrometry, 2000, 6, pp.405 - 408. ⟨10.1255/ejms.362⟩. ⟨hal-01443465⟩
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