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Chapitre D'ouvrage Année : 2016

Telomerisation Reaction of 3,3,3-Trifluoropropene

Résumé

Radical telomerizations of 3,3,3-trifluropropene involving different X-Y chain transfer agents (CTAs, phosphonated, halogenated) was summarized. The kinetics of telomerization enabled one to assess the transfer constants to the CTAs, while cotelomerization have also shown a great interest. The second part deals with the applications of these functional telomers as potential intermediates for the synthesis of well-architectured fluoropolymers including telechelics, block copolymers, macromonomers, graft copolymers. Various examples are supplied to understand the wide potential of applications of these fluoropolymers and potential non-bioaccumulable surfactants. Then, the controlled radical polymerization (CRP or RDRP) of fluoroalkenes in the presence of various chain transfer agents (1-iodofluoroalkanes or xanthates) is also presented. Industrial applications from CRP of fluoroalkenes will illustrate this book chapter.
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Dates et versions

hal-01406586 , version 1 (01-12-2016)

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  • HAL Id : hal-01406586 , version 1

Citer

Georges Kostov, Bruno Ameduri. Telomerisation Reaction of 3,3,3-Trifluoropropene. MODERN SYNTHESIS PROCESSES AND REACTIVITY OF FLUORINATED COMPOUNDS, Elsevier, pp.533-559, 2016, 978-0-12-803740-9. ⟨hal-01406586⟩
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