Self-assembled dimethyldihydropyrene-pyridyl substituted ligands with zinc(II) meso-tetraphenylporphyrin via axial coordination - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Dalton Transactions Année : 2016

Self-assembled dimethyldihydropyrene-pyridyl substituted ligands with zinc(II) meso-tetraphenylporphyrin via axial coordination

Résumé

A series of dimethyldihydropyrene (DHP)-pyridyl photochromic derivatives has been synthesized and its photochemical behaviour characterized by spectroscopic and electrochemical methods. The corresponding noncovalently-linked electron donor–acceptor complexes have been isolated. They combine the DHP-pyridyl ligand as a donor and the zinc(II) tetraphenylporphyrin as acceptor. Such association allowed to explore the efficiency of dative bonds to monitor the interactions between the two units.
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hal-01396518 , version 1 (14-11-2016)

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A. Bakkar, S. Cobo, F. Lafolet, Martial Boggio-Pasqua, G. Royal, et al.. Self-assembled dimethyldihydropyrene-pyridyl substituted ligands with zinc(II) meso-tetraphenylporphyrin via axial coordination. Dalton Transactions, 2016, 45 (41), pp.16453 - 16462. ⟨10.1039/c6dt02975b⟩. ⟨hal-01396518⟩
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