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Article Dans Une Revue Macromolecular Rapid Communications Année : 2014

Bio-Based Aliphatic Polyurethanes Through ADMET Polymerization in Bulk and Green Solvent

Résumé

A new route to ,-diene urethane monomer is proposed by converting 10-undecenoic acid into the corresponding acyl azide, followed by urethanization with 10-undecenol. ADMET polymerizations of this ,-diene urethane monomer as well as other bio-based ,-dienes bearing various organic functions (ester, carbonate, ether, amide) were carried out in bulk and solution conditions. A screening of the most commonly used metathesis catalysts allows to evaluate their tolerance toward the urethane function as well as toward Polarclean, a green and nontoxic high boiling point solvent. The influence of the nature of the central organic function in these ,-diene monomers on the thermomechanical properties is investigated.
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Dates et versions

hal-01366323 , version 1 (26-11-2019)

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Thomas Lebarbé, Arvind S. More, Prakash Sudhir Sane, Etienne Grau, Carine Alfos, et al.. Bio-Based Aliphatic Polyurethanes Through ADMET Polymerization in Bulk and Green Solvent. Macromolecular Rapid Communications, 2014, 35 (4), pp.479-483. ⟨10.1002/marc.201300695⟩. ⟨hal-01366323⟩

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