Ferromagnetic ordering of –[Sm(III)-radical]n– coordination polymers - Archive ouverte HAL
Article Dans Une Revue Chemical Communications Année : 2016

Ferromagnetic ordering of –[Sm(III)-radical]n– coordination polymers

Résumé

[Sm(hfac)3(boaDTDA)]n is the first coordination compound of a thiazyl-based neutral radical ligand to exhibit ferromagnetic ordering; TC = 3 K. The [Sm(III)-radical]n species is soluble in common organic solvents and can be sublimed quantitatively. A McConnell I mechanism is implicated in local exchange pathways that contribute to cooperative magnetic properties.

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Matériaux
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hal-01304285 , version 1 (19-04-2016)

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Elisabeth M. Fatila, Adam C. Maahs, Michelle B. Mills, Mathieu Rouzières, Dmitriy V. Soldatov, et al.. Ferromagnetic ordering of –[Sm(III)-radical]n– coordination polymers. Chemical Communications, 2016, 52, pp. 5414-5417. ⟨10.1039/c6cc01548d⟩. ⟨hal-01304285⟩

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