Synthesis and characterization of conjugated Dawson-type polyoxometalate-porphyrin copolymers - Archive ouverte HAL
Article Dans Une Revue Dalton Transactions Année : 2013

Synthesis and characterization of conjugated Dawson-type polyoxometalate-porphyrin copolymers

Résumé

Hybrid polyoxometalate-porphyrin copolymeric films were obtained by the electro-oxidation of zinc octaethylporphyrin (ZnOEP) in the presence of a Dawson type polyoxophosphovanadotungstate bearing two pyridyl groups (POM(py)(2)). The synthesis of a series of POM(py)(2) consisting of [P2W15V3O62](9-) functionalized with diol-amide or triol moieties, as well as the characterization of the copolymers are presented.
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hal-01238961 , version 1 (07-12-2015)

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Iban Azcarate, Iftikhar Ahmed, Rana Farha, Michel Goldmann, Xiaoxia Wang, et al.. Synthesis and characterization of conjugated Dawson-type polyoxometalate-porphyrin copolymers. Dalton Transactions, 2013, 42 (35), pp.12688-12698. ⟨10.1039/c3dt50850a⟩. ⟨hal-01238961⟩
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