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Article Dans Une Revue Journal of Nanoscience and Nanotechnology Année : 2010

Diethynylbenzene-Based Liquid Crystalline Semiconductor for Solution-Processable Organic Thin-Film Transistors

Pramod Kandoth Madathil
  • Fonction : Auteur
Benoît Heinrich
Bertrand Donnio
  • Fonction : Auteur
Fabrice Mathevet
Daniel Guillon
  • Fonction : Auteur
André-Jean Attias
  • Fonction : Auteur
  • PersonId : 970877
Changjin Lee
  • Fonction : Auteur
Tae-Dong Kim
  • Fonction : Auteur
Kwang-Sup Lee
  • Fonction : Auteur

Résumé

We report here the synthesis and characterization of novel diethynylbenzene-based liquid crystalline semiconductor (P1) for organic thin-film transistors (OTFTs). Compound P1 was synthesized by the Sonogashira coupling reaction between 2-bromo-5-(4-hexylthiophen-2-yl)thieno[3,2-b]thiophene and 1,4-bis(dodecyloxy)-2,5-diethynylbenzene. Top contact OTFTs were fabricated by spin casting with 2 wt% solution of P1 in chloroform and their best performance, which exhibited a hole mobility of 4.5 x 10(-5) cm(2)/Vs, was showed after annealing of the films at liquid crystalline temperature. Time-of-flight (TOF) mobility measured at liquid crystalline phase was observed to be 1.5 x 10(-6) cm(2)/Vs for both positive and negative carriers. These results indicate that the liquid crystallinity helps to improve the molecular packing and enhance charge mobility for P1. These advantages can be applicable to design and construct solution-processable OTFT materials for electronic applications.
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hal-01236821 , version 1 (02-12-2015)

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Pramod Kandoth Madathil, Benoît Heinrich, Bertrand Donnio, Fabrice Mathevet, Jean-Louis Fave, et al.. Diethynylbenzene-Based Liquid Crystalline Semiconductor for Solution-Processable Organic Thin-Film Transistors. Journal of Nanoscience and Nanotechnology, 2010, 10 (10), pp.6800-6804. ⟨10.1166/jnn.2010.2947⟩. ⟨hal-01236821⟩
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