Dual C-F bonding in fluorinated exfoliated graphite. - Archive ouverte HAL
Article Dans Une Revue Journal of Fluorine Chemistry Année : 2015

Dual C-F bonding in fluorinated exfoliated graphite.

Résumé

Accordion-like graphites prepared by exfoliation of a low temperature graphite fluoride were fluorinated using F2 gas in order to be considered as solid lubricants and electrode materials in primary lithium battery. The present work focuses on the fluorination mechanism of such material. In accordance with their high specific surface area, the fluorination is efficient even at room temperature. Whatever the treatment conditions, the accordion-like texture is maintained. The higher the reaction temperature, the higher the atomic ratio F/C. The fluorinated exfoliated graphite exhibit unusual dual Csingle bondF bonding. Both weakened covalent and covalent Csingle bondF bonds coexist. Moreover, the Csingle bondF bond strength is enhanced as a function of the fluorination temperature.

Domaines

Chimie
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Dates et versions

hal-01207998 , version 1 (01-10-2015)

Identifiants

Citer

Maimonatou Mar, Yasser Ahmad, Marc Dubois, Katia Guérin, Nicolas Batisse, et al.. Dual C-F bonding in fluorinated exfoliated graphite.. Journal of Fluorine Chemistry, 2015, 174, pp.36-41. ⟨10.1016/j.jfluchem.2014.07.026⟩. ⟨hal-01207998⟩
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