Nematic liquid crystals of carbon nanotubes and graphene - Archive ouverte HAL
Poster De Conférence Année : 2013

Nematic liquid crystals of carbon nanotubes and graphene

Nicolas Puech
  • Fonction : Auteur
Christophe Blanc
Cécile Zakri
Philippe Poulin
Eric Anglaret
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Résumé

nanotubes or graphene particles. On the other hand, the organization of nanocarbons as liquid crystals provides new methodologies for the still challenging structural characterization of such materials. In this talk, we will present a review of our recent results in the preparation and characterization of lyotropic LC made from concentrated aqueous suspensions, stabilized by surfactants, of single-walled carbon nanotubes (SWNT) or reduced graphene oxide (RGO) [1-5]. Homogeneously oriented SWNT LC can be prepared by shearing a drop between two glass plates [1]. The order parameter of SWNT LC was found to be very sensitive to waviness and entanglement of the nanotubes and the best orientational order was achieved after disentangling, shortening and sorting the nanotubes using ultrasonication and ultracentrifugation [2]. Anisotropic conductive films of nanotubes can be prepared by drying the LC. The anisotropy of conductivity of the anisotropic layers can be related to the order parameter through a simple analytical model assuming that the electrical resistance in a percolation path is proportional to the number of contacts [3]. Homogeneous orientation of RGO LC was achieved by centrifugating capillaries. Structural and thermodynamic characterizations provide statistical information on the dimensions of the graphene flakes, which are found to be comparable with those of neat graphene oxide flakes [4,5]. [1] C. Zamora-Ledezma et al., Nano Lett. 8 (2008) 4103-4107 [2] N. Puech et al., J. Phys. Chem. C. 115 (2011) 3272- 3278 [3] C. Zamora-Ledezma et al., Phys. Rev. E 85 (2012) 062701(5) [4] C. Zamora-Ledezma et al., J. Phys. Chem. Lett., 3 (2012) 2425-2430 [5] C. Zakri et al., Phil. Trans. R. Soc. A. 371 (2013) 201204995(15)
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Dates et versions

hal-01207471 , version 1 (30-09-2015)

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  • HAL Id : hal-01207471 , version 1

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Camilo Zamora-Ledezma, Nicolas Puech, Christophe Blanc, Cécile Zakri, Philippe Poulin, et al.. Nematic liquid crystals of carbon nanotubes and graphene. NT13 Fourteenth International Conference on the Science and Applications of Nanotubes, Jun 2013, Espoo, Finland. ⟨hal-01207471⟩
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