Zero photoelastic and water durable ZnO-SnO-P2O5-B2O3 glasses
Résumé
We report properties of zero birefringent xZnO–(67–x)SnO–(33–y)P2O5–y B2O3 glasses, within 18.5 ≤ x ≤ 22 and y = 0, 3, and 10 mol. %. These compositions of boro-phosphate glasses provide both zero photoelastic constant (PEC) and improved water durability. x = 19 and y = 3 compositions show minimum PEC of −0.002 × 10−12 Pa−1, which can contribute to candidate material for fiber current sensor devise without lead. The structures of zero photoelastic glasses were investigated by Raman scattering and nuclear magnetic resonance spectroscopies. Compositions of zero PEC glasses are explained by the empirical model proposed by Zwanziger et al. [Chem. Mater. 19, 286-290 (2007)].
Domaines
Chimie théorique et/ou physiqueFormat du dépôt | Notice |
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Type de dépôt | Article dans une revue |
Titre |
en
Zero photoelastic and water durable ZnO-SnO-P<sub>2</sub>O<sub>5</sub>-B<sub>2</sub>O<sub>3</sub> glasses
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Résumé |
en
We report properties of zero birefringent <i>x</i>ZnO–(67–<i>x</i>)SnO–(33–<i>y</i>)P<sub>2</sub>O<sub>5</sub>–<i>y</i> B<sub>2</sub>O<sub>3</sub> glasses, within 18.5 ≤ <i>x</i> ≤ 22 and <i>y</i> = 0, 3, and 10 mol. %. These compositions of boro-phosphate glasses provide both zero photoelastic constant (PEC) and improved water durability. <i>x</i> = 19 and <i>y</i> = 3 compositions show minimum PEC of −0.002 × 10<sup>−12</sup> Pa<sup>−1</sup>, which can contribute to candidate material for fiber current sensor devise without lead. The structures of zero photoelastic glasses were investigated by Raman scattering and nuclear magnetic resonance spectroscopies. Compositions of zero PEC glasses are explained by the empirical model proposed by Zwanziger <i>et al</i>. [Chem. Mater. <b>19</b>, 286-290 (2007)].
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Auteur(s) |
A. Saitoh
1
, K. Nakata
1
, G. Tricot
2
, Y. Chen
2
, N. Yamamoto
1
, H. Takebe
1
1
Graduate School of Science and Engineering
( 422616 )
- Japon
2
LASIRE -
Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l'Environnement - UMR 8516
( 1292 )
- LASIRe, anciennement LASIR
-- Université de Lille - Bâtiment C5 (secrétariat), C8 et C4 - 59655 Villeneuve d'Ascq Cedex
- France
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Langue du document |
Anglais
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Nom de la revue |
|
Vulgarisation |
Non
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Comité de lecture |
Oui
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Audience |
Non spécifiée
|
Date de publication |
2015
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Volume |
3
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Page/Identifiant |
046102-1 - 046102-6
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Domaine(s) |
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DOI | 10.1063/1.4917347 |
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