Zero photoelastic and water durable ZnO-SnO-P<sub>2</sub>O<sub>5</sub>-B<sub>2</sub>O<sub>3</sub> glasses - HAL Accéder directement au contenu
Article dans une revue APL Materials Année : 2015

Zero photoelastic and water durable ZnO-SnO-P2O5-B2O3 glasses

Résumé

We report properties of zero birefringent xZnO–(67–x)SnO–(33–y)P2O5y B2O3 glasses, within 18.5 ≤ x ≤ 22 and y = 0, 3, and 10 mol. %. These compositions of boro-phosphate glasses provide both zero photoelastic constant (PEC) and improved water durability. x = 19 and y = 3 compositions show minimum PEC of −0.002 × 10−12 Pa−1, which can contribute to candidate material for fiber current sensor devise without lead. The structures of zero photoelastic glasses were investigated by Raman scattering and nuclear magnetic resonance spectroscopies. Compositions of zero PEC glasses are explained by the empirical model proposed by Zwanziger et al. [Chem. Mater. 19, 286-290 (2007)].
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Dates et versions

hal-01206085, version 1 (28-09-2015)

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A. Saitoh, K. Nakata, G. Tricot, Y. Chen, N. Yamamoto, et al.. Zero photoelastic and water durable ZnO-SnO-P2O5-B2O3 glasses. APL Materials, 2015, 3, pp.046102-1 - 046102-6. ⟨10.1063/1.4917347⟩. ⟨hal-01206085⟩
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