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Article Dans Une Revue Inorganic Chemistry Année : 2015

[RuIII(valen)(CN)2]−: a New Building Block To Design 4d−4f Heterometallic Complexes

Résumé

New 4d−4f heterometallic complexes with a one-dimensional structure, 1∞[{Ru(valen)(CN)2KRu- (valen)(CN)2}{Ln(O2NO)2(CH3OH)3}]·2CH3OH (Ln = Gd, Tb, Dy), have been assembled from the reaction of [K(H2O)2RuIII(valen)(CN)2]·H2O with lanthanide nitrates. The exchange interaction between RuIII and GdIII mediated by the cyanido ligand was determined for the first time and found to be weak and of antiferromagnetic nature.
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hal-01166934 , version 1 (23-06-2015)

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Gabriela Marinescu, Catalin Maxim, Rodolphe Clérac, Marius Andruh. [RuIII(valen)(CN)2]−: a New Building Block To Design 4d−4f Heterometallic Complexes. Inorganic Chemistry, 2015, 54, pp. 5621-5623. ⟨10.1021/acs.inorgchem.5b00889⟩. ⟨hal-01166934⟩
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