Theoretical insights into multibandgap hybrid perovskites for photovoltaic applications - Archive ouverte HAL
Communication Dans Un Congrès Année : 2015

Theoretical insights into multibandgap hybrid perovskites for photovoltaic applications

Résumé

This paper reviews some of the recent theoretical investigations on the Rashba Dresselhaus spin effects and dielectric properties of CH3NH3PbI3 hybrid perovskites and CsPbI3 all-inorganic perovskites using Density functional theory. The spin vectors rotate in the non-centrosymmetric P4mm tetragonal phase, respectively clockwise and counterclockwise, in a manner that is characteristic of a pure Rashba effect. The high frequency dielectric constants ε∞ of MAPbI3 and CsPbI3 are similar as anticipated, since large differences are only expected at very low frequency where additional contributions from molecular reorientations show off for the hybrid compounds. A first simulation of a perovskite on silicon tandem cell, including a tunnel junction, is also investigated. Effect of halogen substitution (I/Br) is inspected, revealing limitations for short-circuit current and open-circuit voltage electrical characteristics.
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Dates et versions

hal-01162198 , version 1 (09-06-2015)

Identifiants

  • HAL Id : hal-01162198 , version 1

Citer

Jacky Even, Laurent Pedesseau, Mikaël Kepenekian, Daniel Sapori, Claudine Katan. Theoretical insights into multibandgap hybrid perovskites for photovoltaic applications. SPIE Optics+Photonics - Nanoscience+Engineering 2015, Aug 2015, San Diego, United States. pp.95520Z. ⟨hal-01162198⟩
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