Floquet-Magnus expansion for general N-coupled spins systems in magic-angle spinning nuclear magnetic resonance Spectra - Archive ouverte HAL
Article Dans Une Revue Chemical Physics Année : 2015

Floquet-Magnus expansion for general N-coupled spins systems in magic-angle spinning nuclear magnetic resonance Spectra

Résumé

Abstract In this paper we present a theoretical perturbative approach for describing the NMR spectrum of strongly dipolar-coupled spin systems under fast magic-angle spinning. Our treatment is based on two approaches: the Floquet approach and the Floquet-Magnus expansion. The Floquet approach is well known in the NMR community as a perturbative approach to get analytical approximations. Numerical procedures are based on step-by-step numerical integration of the corresponding differential equations. The Floquet-Magnus expansion is a perturbative approach of the Floquet theory. Furthermore, we address the “ γ - encoding” effect using the Floquet-Magnus expansion approach. We show that the average over “ γ ” angle can be performed for any Hamiltonian with γ symmetry.
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Dates et versions

hal-01157460 , version 1 (28-05-2015)

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Eugene Stephane Mananga, Thibault Charpentier. Floquet-Magnus expansion for general N-coupled spins systems in magic-angle spinning nuclear magnetic resonance Spectra. Chemical Physics, 2015, 450–451, pp.83-90. ⟨10.1016/j.chemphys.2015.02.006⟩. ⟨hal-01157460⟩
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