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Article Dans Une Revue Chemical Communications Année : 2014

Co-catalytic oxidative coupling of primary amines to imines using an organic nanotube-gold nanohybrid

Résumé

A novel nanohybrid structure was synthesized by assembling gold nanoparticles on polymerized polydiacetylene nanotubes. Combination of the nanohybrid with gallacetophenone afforded an efficient cooperative co-catalytic system for the oxidative coupling of primary amines into imines. The system is highly efficient and sustainable as it operates in high yields using minimal amounts of the metal and the quinone, under ambient atmosphere, at room temperature, in water, and is easily recycled.
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Dates et versions

hal-01157190 , version 1 (13-11-2015)

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Dhanaji V. Jawale, Edmond Gravel, Elise Villemin, Nimesh Shah, Valerie Geertsen, et al.. Co-catalytic oxidative coupling of primary amines to imines using an organic nanotube-gold nanohybrid. Chemical Communications, 2014, 50 (96), pp.15251-15254. ⟨10.1039/c4cc07951e⟩. ⟨hal-01157190⟩
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