Structural factors impacting carrier transport and electroluminescence from Si nanocluster-sensitized Er ions
Résumé
We present an analysis of factors influencing carrier transport
and electroluminescence (EL) at 1.5 μm from erbium-doped silicon-rich
silica (SiOx) layers. The effects of both the active layer thickness and the Siexcess
content on the electrical excitation of erbium are studied. We
demonstrate that when the thickness is decreased from a few hundred to
tens of nanometers the conductivity is greatly enhanced. Carrier transport is
well described in all cases by a Poole-Frenkel mechanism, while the
thickness-dependent current density suggests an evolution of both density
and distribution of trapping states induced by Si nanoinclusions. We ascribe
this observation to stress-induced effects prevailing in thin films, which
inhibit the agglomeration of Si atoms, resulting in a high density of sub-nm
Si inclusions that induce traps much shallower than those generated by Si
nanoclusters (Si-ncs) formed in thicker films. There is no direct correlation
between high conductivity and optimized EL intensity at 1.5 μm. Our
results suggest that the main excitation mechanism governing the EL signal
is impact excitation, which gradually becomes more efficient as film
thickness increases, thanks to the increased segregation of Si-ncs, which in
turn allows more efficient injection of hot electrons into the oxide matrix.
Optimization of the EL signal is thus found to be a compromise between
conductivity and both number and degree of segregation of Si-ncs, all of
which are governed by a combination of excess Si content and sample
thickness. This material study has strong implications for many electricallydriven
devices using Si-ncs or Si-excess mediated EL