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Article Dans Une Revue Journal of the American Chemical Society Année : 2013

Azaphosphatranes as Structurally Tunable Organocatalysts for Carbonate Synthesis from CO2 and Epoxides

Résumé

Three azaphosphatranes were used as organocatalysts for the synthesis of cyclic carbonates from CO2 and epoxides. They proved to be efficient single-component, metal-free catalysts for the reaction of simple or activated epoxides (styrene oxide, epichlorohydrin, glycidyl methyl ether) with CO2 under mild reaction conditions, displaying high stability and productivity over several days of reaction. Substitution patterns on the catalyst were shown to affect activity and stability. Kinetic analysis allowed investigation of the reaction mechanism.
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hal-01117422 , version 1 (17-02-2015)

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Bastien Chatelet, Lionel Joucla, Jean-Pierre Dutasta, Alexandre Martinez, Kai C. Szeto, et al.. Azaphosphatranes as Structurally Tunable Organocatalysts for Carbonate Synthesis from CO2 and Epoxides. Journal of the American Chemical Society, 2013, 135 (14), pp.5348-5351. ⟨10.1021/ja402053d⟩. ⟨hal-01117422⟩
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