Article Dans Une Revue Journal of electroanalytical chemistry and interfacial electrochemistry Année : 2015

The impedance response of rotating disk electrodes

Résumé

Classifications and recent findings are reviewed for numerical simulations describing the impedance response of rotating disk electrodes. The disk geometry is shown to cause a complex character to the ohmic contribution to the impedance response. For reactions that do not involve formation of adsorbed intermediates, the frequency dispersion associated with the disk geometry occurs above a characteristic frequency. Such dispersion may be avoided by selecting a disk of sufficiently small dimension. For reactions that do involve formation of adsorbed intermediates, a low-frequency dispersion is also seen. Models including the influence of mass transfer show that the coupling of faradaic and charging currents induces frequency dispersion at frequencies associated with the faradaic reaction.

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hal-01111367 , version 1 (30-01-2015)

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Shao-Ling Wu, Mark E. Orazem, Bernard Tribollet, Vincent Vivier. The impedance response of rotating disk electrodes. Journal of electroanalytical chemistry and interfacial electrochemistry, 2015, 737, pp.11-22. ⟨10.1016/j.jelechem.2014.05.036⟩. ⟨hal-01111367⟩
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