Auto-click’ functionalization for diversified copper(I) and gold(I) NHCs - Archive ouverte HAL
Article Dans Une Revue Dalton Transactions Année : 2014

Auto-click’ functionalization for diversified copper(I) and gold(I) NHCs

Résumé

Azide-tagged CuI-NHC reacts in an ‘auto-click’ process to furnish complexes functionalized by 1,2,3-triazoles bearing diverse substituents. The resulting CuI complexes are amenable to further transmetallation to AuI. The whole strategy proceeds with mild conditions and constitutes an efficient entry to functionalised metal-NHCs with biorelevant moieties.

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Chimie

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https://hal.science/hal-01081329

Soumis le : vendredi 7 novembre 2014-15:12:25

Dernière modification le : jeudi 25 avril 2024-10:08:15

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Dates et versions

hal-01081329 , version 1 (07-11-2014)

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Houssein Ibrahim, Clémentine Gibard, Cédric Hesling, Régis Guillot, Laurent Morel, et al.. Auto-click’ functionalization for diversified copper(I) and gold(I) NHCs. Dalton Transactions, 2014, 43, pp.6981-6989. ⟨10.1039/C4DT00429A⟩. ⟨hal-01081329⟩

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