Cyclopentadienyl N-heterocyclic carbene-nickel complexes as efficient pre-catalysts for the hydrosilylation of imines. - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Catalysis Science & Technology Année : 2013

Cyclopentadienyl N-heterocyclic carbene-nickel complexes as efficient pre-catalysts for the hydrosilylation of imines.

Résumé

The in situ generated nickel hydride complex, [Ni(Mes2NHC)HCp], and its cationic analog, [Ni(Mes2NHC)(NCMe)Cp](PF6), are efficient and chemoselective pre-catalysts for the hydrosilylation of both aldimines and ketimines under mild conditions. [on SciFinder(R)]
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Dates et versions

hal-01069725 , version 1 (29-09-2014)

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Linus P. Bheeter, Mickael Henrion, Michael J. Chetcuti, Christophe Darcel, Vincent Ritleng, et al.. Cyclopentadienyl N-heterocyclic carbene-nickel complexes as efficient pre-catalysts for the hydrosilylation of imines.. Catalysis Science & Technology, 2013, 3, pp.3111--3116. ⟨10.1039/c3cy00514c⟩. ⟨hal-01069725⟩
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