Trans-1,2-disiloxybenzocyclobutene, an adequate partner for the auto-oxisation: EPR/spin trapping and theoretical studies
Résumé
The auto-oxidation of trans-1,2-disiloxybenzocyclobutene was found to be very efficient, giving endoperoxide in quantitative yield. Each step of the mechanism of spin-forbidden addition of triplet oxygen O2 was studied by both EPR/spin trapping and theoretical studies.
Domaines
Chimie organiqueOrigine | Fichiers éditeurs autorisés sur une archive ouverte |
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