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Article Dans Une Revue Microporous and Mesoporous Materials Année : 2014

Effect of the ligand functionalization on the acid-base properties of flexible MOFs

Thomas Devic
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Patricia Horcajada
Christian Serre
Guillaume Clet
Marco Daturi

Résumé

The nature of the sites contributing to the acid-base properties of the functionalized highly flexible MIL-53(Fe)-X MOFs, X = CH3, Cl, Br was assessed by Infrared measurements using propyne as a probe molecule since it could act as a proton acceptor via its Ctriple bond; length of mdashC triple bond and as a proton donor through the triple bond; length of mdashCsingle bondH group. These experiments performed in a wide range of propyne concentration were coupled with Density Functional Theory (DFT) calculations performed for all the propyne/MIL-53(Fe) systems based on structures simulated from the in situ X-ray Powder diffraction data. This joint experimental-modeling approach evidenced that the bridging hydroxyl groups present in the MOF structure free of any intra-framework interactions play a preponderant role in the interaction with propyne as hydrogen donor but also as basic sites through the O atom for all functionalized MIL-53(Fe) solids. For X = Cl and Br, an additional interaction is evidenced at higher propyne concentration, involving the halogen atom, which plays the role of basic site toward propyne. These findings are further discussed in light of complementary experimental data issued from gravimetry and microcalorimetry measurements.

Domaines

Matériaux
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Dates et versions

hal-01064278 , version 1 (16-09-2014)

Identifiants

Citer

Béatrice Moulin, Fabrice Salles, Sandrine Bourrelly, P. L. Llewellyn, Thomas Devic, et al.. Effect of the ligand functionalization on the acid-base properties of flexible MOFs. Microporous and Mesoporous Materials, 2014, 195, pp.197-204. ⟨10.1016/j.micromeso.2014.04.025⟩. ⟨hal-01064278⟩
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