Liquid-liquid extraction and quantitative determination of tungsten(VI) using macrocyclic reagent (DB-18-C-6) as a thiocyanate complex [WO (SCN)5]2- - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Desalination and Water Treatment Année : 2013

Liquid-liquid extraction and quantitative determination of tungsten(VI) using macrocyclic reagent (DB-18-C-6) as a thiocyanate complex [WO (SCN)5]2-

Résumé

In recent years, the extraction using crown ethers has reached a resounding success in different scientific and technical fields. In this work, the authors report the results of the main steps of extraction and determination (proportioning) of the tungsten ion (VI) using a chloroformed solution of crown ether. The dibenzo-18-C-6(2,3,11,12-dibenzo-1,4,7,10,13,16-hexaoxacyclooctadeca-2,11-diene according to the IUPAC systematic nomenclature). The identification and quantification of W(VI) using the absorption spectrum, the influence of the necessary reagents, the needed acidity level for complete extraction and complexation of W(VI) using a crown ether, and the influence of multivalent metal ions were examined, considering that the sensitivity, selectivity, and detection limits have been determined. This system obeys Beer's law in the range of 0.18-18.3 μg cm−3of tungsten with a molar absorption of 1.6 × 104 mol−1 cm−1 at 415 nm and the detection, quantification limits were, respectively, equal to 0.7-1.8 μg cm−3. The developed method was applied for the extraction of W(VI) in the high speed steel (HSS): HS2-9-1-8 containing 2% W, 9% Mo, 1% V, and 8% Co.
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Dates et versions

hal-01064198 , version 1 (15-09-2014)

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A. Saoud, Noureddine Nasrallah, Abdeltif Amrane, A.M. Nabieva, B. Hamada, et al.. Liquid-liquid extraction and quantitative determination of tungsten(VI) using macrocyclic reagent (DB-18-C-6) as a thiocyanate complex [WO (SCN)5]2-. Desalination and Water Treatment, 2013, 55 (25-27), pp.4928-4934. ⟨10.1080/19443994.2013.809962⟩. ⟨hal-01064198⟩
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