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Article Dans Une Revue CrystEngComm Année : 2013

Side functionalization of diboronic acid precursors for covalent organic frameworks

Résumé

A series of substituted 1,4-benzenediboronic acids (BDBA) was synthesized and their thermal properties investigated. Two diboronic acids were studied as building-blocks for covalent organic framework (COF) formation, namely 2,5-dimethoxy-1,4-benzenediboronic acid and 2-nitro-1,4-benzeneboronic acid. Interestingly, substitution of the BDBA core caused a dramatic decrease of the polymerization temperature leading to the formation of a less organized structure.

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Matériaux
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Dates et versions

hal-01020191 , version 1 (07-07-2014)

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Thomas Faury, Frédéric Dumur, Sylvain Clair, Mathieu Abel, Louis Porte, et al.. Side functionalization of diboronic acid precursors for covalent organic frameworks. CrystEngComm, 2013, 15, pp.2067-2075. ⟨10.1039/c3ce26494g⟩. ⟨hal-01020191⟩
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