Synthesis of Branched Polymers under Continuous-Flow Microprocess: An Improvement of the Control of Macromolecular Architectures - Archive ouverte HAL Access content directly
Journal Articles Macromolecular Rapid Communications Year : 2011

Synthesis of Branched Polymers under Continuous-Flow Microprocess: An Improvement of the Control of Macromolecular Architectures

Abstract

Polymerization reactions can benefit from continuous-flow microprocess in terms of kinetics control, reactants mixing or simply efficiency when high-throughput screening experiments are carried out. In this work, we perform for the first time the synthesis of branched macromolecular architecture through a controlled/living' polymerization technique, in tubular microreactor. Just by tuning process parameters, such as flow rates of the reactants, we manage to generate a library of polymers with various macromolecular characteristics.

Dates and versions

hal-00956834 , version 1 (07-03-2014)

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Florence Bally, Christophe A. Serra, Cyril Brochon, Georges Hadziioannou. Synthesis of Branched Polymers under Continuous-Flow Microprocess: An Improvement of the Control of Macromolecular Architectures. Macromolecular Rapid Communications, 2011, 32 (22), pp.1820-1825. ⟨10.1002/marc.201100429⟩. ⟨hal-00956834⟩

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CNRS INC-CNRS LCPO
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