DNA vs. Mirror-Image DNA: A Universal Approach to Tune the Absolute Configuration in DNA-Based Asymmetric Catalysis. - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Angewandte Chemie International Edition Année : 2013

DNA vs. Mirror-Image DNA: A Universal Approach to Tune the Absolute Configuration in DNA-Based Asymmetric Catalysis.

Résumé

Mirror mirror on the wall: By taking advantage of the unique structural features of L-DNA, the first examples of left-helical enantioselective induction in the field of DNA-based asymmetric catalysis were realized. Most importantly, this approach is the only one that allows a reliable and predictable access to both enantiomers for any given reaction.

Domaines

Chimie organique

Dates et versions

hal-00952330 , version 1 (26-02-2014)

Identifiants

Citer

Jocelyn Wang, Erica Beneditti, Lucas Bethge, Stefan Vonhoff, Sven Klussmann, et al.. DNA vs. Mirror-Image DNA: A Universal Approach to Tune the Absolute Configuration in DNA-Based Asymmetric Catalysis.. Angewandte Chemie International Edition, 2013, 52 (44), pp.11546-11549. ⟨10.1002/anie.201306232⟩. ⟨hal-00952330⟩
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