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Article Dans Une Revue Angewandte Chemie International Edition Année : 2013

Base-Catalyzed Electrophilic Trifluoromethylthiolation of Terminal Alkynes

Résumé

Pin the tail on the alkyne: CF3S- or CF3CF2S-alkynes can be simply and quickly obtained by mixing terminal alkynes with a trifluoromethanesulfenamide reagent. The reaction uses easy-to-handle reagents, and functions under mild conditions without activation by transition metals.

Dates et versions

hal-00948085 , version 1 (17-02-2014)

Identifiants

Citer

S. Alazet, L. Zimmer, T. Billard. Base-Catalyzed Electrophilic Trifluoromethylthiolation of Terminal Alkynes. Angewandte Chemie International Edition, 2013, 52 (41), pp.10814-10817. ⟨10.1002/anie.201305179⟩. ⟨hal-00948085⟩
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