Adiabatic electron affinities of (AgF)n clusters: Experiment and DFT calculations - Archive ouverte HAL Access content directly
Journal Articles Chemical Physics Letters Year : 2008

Adiabatic electron affinities of (AgF)n clusters: Experiment and DFT calculations

Jean-Marc L'Hermite
Pierre Labastie
  • Function : Author
  • PersonId : 917516

Abstract

We present a joint theoretical and experimental investigation of small neutral and anionic silver fluoride clusters View the MathML source(AgF)n(-) with n ⩽ 6. We have measured the electron detachment energies of the anions View the MathML source(AgF)n- and determined the adiabatic electron affinities of neutral (AgF)n clusters. Ab initio calculations in the framework of the density functional theory have been performed to investigate the electronic and structural properties of both neutral and anionic species. The localization of the excess electron in the anion is discussed.
Fichier principal
Vignette du fichier
article_agf.pdf (757.76 Ko) Télécharger le fichier
Origin Files produced by the author(s)

Dates and versions

hal-00945895 , version 1 (28-05-2021)

Identifiers

Cite

Franck Rabilloud, O. Bonhomme, Jean-Marc L'Hermite, Pierre Labastie. Adiabatic electron affinities of (AgF)n clusters: Experiment and DFT calculations. Chemical Physics Letters, 2008, 454 (4-6), pp.153-157. ⟨10.1016/j.cplett.2008.02.003⟩. ⟨hal-00945895⟩
128 View
55 Download

Altmetric

Share

Gmail Mastodon Facebook X LinkedIn More