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Article Dans Une Revue Inorganic Chemistry Année : 2014

Efficient Fluorinating Agent through Topochemical Fluorination of Co−Fe Layered Double Hydroxides

Résumé

Mixed-metal inorganic fluoride, Co0.60Fe0.40F3, solid solutions are obtained through topochemical reactions of Co2FeCl(OH)6*2H2O LDH with molecular fluorine, F2, at temperatures as low as 100 °C. This solid solution possesses interesting F*-releasing ability, and its efficiency as a solid-state fluorinating agent is demonstrated on a commercial polyethylene film. 19F solid state NMR and contact angle measurements underline the efficient fluorination of this polymer.
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Dates et versions

hal-00927628 , version 1 (13-01-2014)

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Nicolas Louvain, Jérémy Peyroux, Marc Dubois, Wikenson Simond, Fabrice Leroux. Efficient Fluorinating Agent through Topochemical Fluorination of Co−Fe Layered Double Hydroxides. Inorganic Chemistry, 2014, 53, pp.852-860. ⟨10.1021/ic402193x⟩. ⟨hal-00927628⟩
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