Fabrication and characterization of anode-supported single chamber solid oxide fuel cell based on La<sub>0.6</sub>Sr<sub>0.4</sub>Co<sub>0.2</sub>Fe<sub>0.8</sub>O<sub>3−δ</sub>-Ce<sub>0.9</sub>Gd<sub>0.1</sub>O<sub>1.95</sub> composite cathode - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue International Journal of Hydrogen Energy Année : 2014

Fabrication and characterization of anode-supported single chamber solid oxide fuel cell based on La0.6Sr0.4Co0.2Fe0.8O3−δ-Ce0.9Gd0.1O1.95 composite cathode

Résumé

Anode-supported solid oxide fuel cells consisting of nickel-gadolinium doped ceria (NiO-CGO, 60:40 wt%) anode, gadolinium doped ceria (CGO) electrolyte and lanthanum strontium cobaltite ferrite-gadolinium doped ceria (LSCF-CGO) cathode are developed and operated under single-chamber conditions, utilizing methane/air mixture. The cell performance is optimized regarding the electrolyte microstructure, cathode composition and testing conditions. The performance of the cell improves with the decrease of the thickness of the electrolyte and the increase of the ratio of methane to oxygen. The test cell with LSCF-CGO cathode (70:30 wt%) that was sintered at 1100 °C for 2 h and 150 μm dense electrolyte exhibits the maximum power output of ∼260 mW cm−2 at 600 °C in CH4/O2 = 2 atmosphere.
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Dates et versions

hal-00918061 , version 1 (12-12-2013)

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Li-Ping Sun, Mathilde Rieu, Jean-Paul Viricelle, Christophe Pijolat, Hui Zhao. Fabrication and characterization of anode-supported single chamber solid oxide fuel cell based on La0.6Sr0.4Co0.2Fe0.8O3−δ-Ce0.9Gd0.1O1.95 composite cathode. International Journal of Hydrogen Energy, 2014, 39 (2), pp.1014-1022. ⟨10.1016/j.ijhydene.2013.10.117⟩. ⟨hal-00918061⟩
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