Chiral Cyclopentadienyl-type Ligands: a New Breakthrough for Asymmetric C[BOND]H Functionalisation
Résumé
Ligand breakthrough: Using a well-designed chiral cyclopentadienyl rhodium complex as the catalyst, an efficient asymmetric C[BOND]H bond functionalization/cyclization was performed at RT in the presence of a catalytic amount of dibenzoylperoxide (DBPO) leading to tetrahydroiso-quinolinone derivatives with moderate to good yields and very good enantiomeric ratios.