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Article Dans Une Revue Organic Letters Année : 2011

New chiral cyclooctatriene-based polycyclic architectures.

Résumé

The synthesis and properties of new chiral polycyclic architectures that display both helicity and a saddle-type shape are described. The enantiomers have been separated, and their absolute configuration was determined by VCD and ECD. The unprecedented molecular architecture is based on a cyclooctatriene core surrounded by an association of benzo[c]fluorene and ortho-phenylene units.
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Dates et versions

hal-00875479 , version 1 (22-10-2013)

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Grégory Pieters, Anne Gaucher, Jérôme Marrot, François Maurel, Jean-Valère Naubron, et al.. New chiral cyclooctatriene-based polycyclic architectures.. Organic Letters, 2011, 13 (16), pp.4450-3. ⟨10.1021/ol201804h⟩. ⟨hal-00875479⟩
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