First enantioselective iron-porphyrin-catalyzed sulfide oxidation with aqueous hydrogen peroxide. - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Chemical Communications Année : 2011

First enantioselective iron-porphyrin-catalyzed sulfide oxidation with aqueous hydrogen peroxide.

Résumé

The asymmetric oxidation of sulfides by H(2)O(2) to give optically active sulfoxides (ee up to 90%) was carried out in methanol and water using chiral water-soluble iron porphyrins as catalysts.

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Dates et versions

hal-00869878 , version 1 (04-10-2013)

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Paul Le Maux, Gérard Simonneaux. First enantioselective iron-porphyrin-catalyzed sulfide oxidation with aqueous hydrogen peroxide.. Chemical Communications, 2011, 47 (24), pp.6957-9. ⟨10.1039/c1cc11675d⟩. ⟨hal-00869878⟩
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