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Article Dans Une Revue Organic Letters Année : 2012

SN2′ Reaction of Allylic Difluorides with Lithium Amides and Thiolates

Résumé

The synthesis of monofluoroalkenes using an SN2′ reaction of lithium amides derived from aromatic amines or lithium thiolates with 3,3-difluoropropenes is reported. This transformation features the use of fluoride as a leaving group.
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Dates et versions

hal-00866779 , version 1 (27-09-2013)

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Maxime Bergeron, David Guyader, Jean-François Paquin. SN2′ Reaction of Allylic Difluorides with Lithium Amides and Thiolates. Organic Letters, 2012, 14 (23), pp.5888-5891. ⟨10.1021/ol302802r⟩. ⟨hal-00866779⟩
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