Methane oxidation by lattice oxygen of Ni/BaTi1-xInxO3-delta catalysts - Archive ouverte HAL
Article Dans Une Revue Catalysis Today Année : 2010

Methane oxidation by lattice oxygen of Ni/BaTi1-xInxO3-delta catalysts

E. Gautron
F. Mondragon
  • Fonction : Auteur
A. Moreno

Résumé

BaTi1−xInxO3−δ perovskites (called BITx) were evaluated as supports of nickel catalysts for methane oxidation in the absence of gas-phase oxygen. Ni/BaTi1−xInxO3−δ (x=0 and 0.3) catalysts were studied, by temperature programmed surface reaction of methane (TPSR-CH4) and pulses at 850°C. In these conditions, the only oxygen source is the oxide bulk support. TPSR-CH4 results suggest that the support is able to oxidize the methane producing H2 and CO at temperatures above 750°C. Ni/BT and Ni/BIT0.7 catalysts, showed a high selectivity towards partial oxidation products. Ni/BIT0.7 catalyst was more stable than Ni/BT due to the existence of Ni-In alloys which catalyze less the cracking reaction. Moreover, the higher ionic conductivity of BIT0.7 facilitates the O2− ions diffusion to the surface and promotes the oxidation of carbonaceous deposits formed on the metal-support interface preventing thus catalyst deactivation.

Dates et versions

hal-00848888 , version 1 (29-07-2013)

Identifiants

Citer

V. Garcia, Maria Teresa Caldes, O. Joubert, E. Gautron, F. Mondragon, et al.. Methane oxidation by lattice oxygen of Ni/BaTi1-xInxO3-delta catalysts. Catalysis Today, 2010, 157 (1-4), pp.177-182. ⟨10.1016/j.cattod.2010.01.021⟩. ⟨hal-00848888⟩
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