Article Dans Une Revue Inorganic Chemistry Année : 2013

Revisiting the Spectroscopy of the Bi3+ Ion in Oxide Compounds.

Philippe Boutinaud
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Résumé

A model is introduced to predict the energy of metal-to-metal charge-transfer transitions in oxide compounds containing Bi3+ ions and d0 or d10 metals (Mn+). The model takes into account the structural characteristics of the host lattices, the anion relaxation resulting from Bi3+ doping, and the electronegativities and coordination numbers of the Bi3+ and Mn+ ions in the compounds. It is shown, through a critical review of the archival literature, that this model provides new insights on the assignment of the luminescence spectra and the related interpretation of the spectroscopic behaviors.

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Dates et versions

hal-00847455 , version 1 (23-07-2013)

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  • HAL Id : hal-00847455 , version 1

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Philippe Boutinaud. Revisiting the Spectroscopy of the Bi3+ Ion in Oxide Compounds.. Inorganic Chemistry, 2013, 52, pp.6028-6038. ⟨hal-00847455⟩
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