Article Dans Une Revue Acta Crystallographica Section E : Structure Reports Online [2001-2014] Année : 2013

Tris(1,10-phenanthroline-kappa(2) N,N')iron(II) bis-(1,1,3,3-tetra-cyano-2-eth-oxy-propenide) hemihydrate.

Résumé

In the title hydrated mol-ecular salt, [Fe(C12H8N2)3](C9H5N4O)2*0.5H2O, the water mol-ecule site is half-occupied. The Fe-N bond lengths within the octa-hedral tris-chelate [Fe(phen)3](2+) ion (phen is 1,10-phenantroline) are indicative of a low-spin d(6) electronic configuration for the metal ion. The C-N, C-C and C-O bond lengths in the polynitrile anions indicate extensive electronic delocalization. In the crystal, the components are linked through O-H⋯N hydrogen bonds, forming [100] chains, as well as through Coulombic inter-actions
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Dates et versions

hal-00812711 , version 1 (12-04-2013)

Identifiants

  • HAL Id : hal-00812711 , version 1

Citer

Zouaoui Setifi, Fatima Setifi, Seik Weng Ng, Abdelghani Oudahmane, Malika El-Ghozzi, et al.. Tris(1,10-phenanthroline-kappa(2) N,N')iron(II) bis-(1,1,3,3-tetra-cyano-2-eth-oxy-propenide) hemihydrate.. Acta Crystallographica Section E : Structure Reports Online [2001-2014], 2013, 69, pp.m12-13. ⟨hal-00812711⟩
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