Catalytic enantioselective [4 + 2]-cycloaddition: a strategy to access aza-hexacycles. - Archive ouverte HAL Access content directly
Journal Articles Chemical Society Reviews Year : 2013

Catalytic enantioselective [4 + 2]-cycloaddition: a strategy to access aza-hexacycles.

Claudia Lalli
Guillaume Dagousset

Abstract

The aza-Diels Alder reaction has become one of the most widely used synthetic tools for the preparation of N-containing 6-membered heterocycles. Numerous important developments have been reported to render this reaction catalytic and enantioselective. This tutorial review highlights strategies and recent advances to achieve high efficiency and selectivity through the use of organocatalysts and transition metal complexes, allowing also the extension of this transformation substrate scope.
No file

Dates and versions

hal-00807909 , version 1 (04-04-2013)

Identifiers

Cite

Géraldine Masson, Claudia Lalli, Meryem Benohoud, Guillaume Dagousset. Catalytic enantioselective [4 + 2]-cycloaddition: a strategy to access aza-hexacycles.. Chemical Society Reviews, 2013, 42 (3), pp.902-23. ⟨10.1039/c2cs35370a⟩. ⟨hal-00807909⟩
33 View
0 Download

Altmetric

Share

Gmail Facebook X LinkedIn More