CuAAC Functionalization of Azide-Tagged Copper(I)-NHCs Acting as Catalyst and Substrate - Archive ouverte HAL
Article Dans Une Revue Organometallics Année : 2012

CuAAC Functionalization of Azide-Tagged Copper(I)-NHCs Acting as Catalyst and Substrate

Résumé

Azide-tagged copper(I) complexes of N-heterocyclic carbenes (NHCs) analogous to the well-known bis[2,6- diisopropylphenyl]imidazol-2-ylidene (IPr) and bis[2,6-diisopropylphenyl]imidazolin-2-ylidene (SIPr) were synthesized and characterized. These complexes were able to act as catalyst and substrate in a model copper-catalyzed azide−alkyne (CuAAC) reaction with propargyl alcohol, yielding functionalized copper(I)-NHC complexes.

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https://hal.science/hal-00785150

Soumis le : mardi 5 février 2013-14:57:52

Dernière modification le : vendredi 19 avril 2024-09:44:36

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Dates et versions

hal-00785150 , version 1 (05-02-2013)

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  • HAL Id : hal-00785150 , version 1

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Clémentine Gibard, Daniel Avignant, Federico Cisnetti, Arnaud Gautier. CuAAC Functionalization of Azide-Tagged Copper(I)-NHCs Acting as Catalyst and Substrate. Organometallics, 2012, 31, pp.7902-7908. ⟨hal-00785150⟩

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