When two non-interacting plane impulsive gravitational waves undergo a head-on collision, the vacuum interaction region between the waves after the collision contains backscattered gravitational radiation from both waves. The two systems of backscattered waves have each got a family of rays (null geodesics) associated with them. We demonstrate that if it is assumed that a parameter exists along each of these families of rays such that the modulus of the complex shear of each is equal then Einstein's vacuum field equations, with the appropriate boundary conditions, can be integrated systematically to reveal the well-known solutions in the interaction region. In so doing the mystery behind the origin of such solutions is removed. With the use of the field equations it is suggested that the assumption leading to their integration may be interpreted physically as implying that the energy densities of the two backscattered radiation fields are equal. With the use of different boundary conditions this approach can lead to new collision solutions.