In this paper, via the algebra of generalized functions, we investigate the generalized Riemann's problem associated to conservation laws with analytical coefficients. This allows us to transform the problem into a system of ordinary differential equations. In some particular cases, such that Burgers' and conservative Richard's equation, approximated solutions are obtained by the truncation of the so called Hugoniot-Maslov's chain and numerical simulations are also presented in the case of equations with polynomial coefficients.