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Article Dans Une Revue Organic Letters Année : 2013

Straightforward Synthesis of a Double-Lasso Macrocycle from a Nonsymmetrical [c2]Daisy Chain

Résumé

The straightforward synthesis of a double-lasso macrocycle from a nonsymmetrical [c2]daisy chain, using the copper(I)-catalyzed Huisgen alkyne azide 1,3-dipolar cycloaddition, is described. The preparation of the nonsymmetrical alkyne azide [c2]daisy chain precursor was realized in situ via the exchange of the monomers contained in both symmetrical alkyne and azide [c2]daisy chains and was followed by mass spectrometry.

Domaines

Chimie organique
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Dates et versions

hal-00770586 , version 1 (07-01-2013)

Identifiants

Citer

Camille Romuald, Guillaume Cazals, Christine Enjalbal-Goubet, Frédéric Coutrot. Straightforward Synthesis of a Double-Lasso Macrocycle from a Nonsymmetrical [c2]Daisy Chain. Organic Letters, 2013, 15 (1), pp.184-187. ⟨10.1021/ol303186j⟩. ⟨hal-00770586⟩
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