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Article Dans Une Revue European Journal of Organic Chemistry Année : 2009

Synthesis of secondary 2-amino thiols and/or their disulfides via thiazolinium salts

Résumé

Commercially available β-amino alcohols have been transformed into various secondary β-amino thiols and/or their disulfides by using methyl dithioacetate as a source of sulfur. The transformation involves a thiazolinium salt as a versatile key intermediate, which enables easy modulation of the product structure by varying the substituents on the heterocycle and the N-alkylating agent.

Domaines

Chimie organique
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Dates et versions

hal-00717154 , version 1 (12-07-2012)

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Citer

Guillaume Mercey, Jean-François Lohier, Annie-Claude Gaumont, Jocelyne Levillain, Mihaela Gulea. Synthesis of secondary 2-amino thiols and/or their disulfides via thiazolinium salts. European Journal of Organic Chemistry, 2009, 25, pp.4357-4364. ⟨10.1002/ejoc.200900514⟩. ⟨hal-00717154⟩
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